Sum frequency generation spectroscopy of simulated. Perry university of south florida follow this and additional works at. Sum frequency generation sfg vibrational spectroscopy, atomic force microscopy afm, and other complementary surfacesensitive techniques have been used to study the surface molecular structure and surface mechanical behavior of biologicallyrelevant polymer systems. Recently, an emerging technique, sumfrequency generation vibrational sfg spectroscopy was applied to the analysis of proteins adsorbed at various interfaces. It explains the use of advances in two frontier research areas. In this work, we show that, by employing a prism geometry, total internal reflection sum frequency generation sfg vibrational spectroscopy allows for characterizing mesoscopic materials with irregular or complex surfaces. Sum frequency generation sfg vibrational spectroscopy applies two laser beams that interact with the system of interest simultaneously 3436, 6669, one with visible e. Introduction sum frequency generation sfg vibrational spectroscopy can be used to study many types of surfaces and interfaces, but this entry will focus on studies. Sfg vibrational spectra for a selfassembled monolayer of octadecanethiol were investigated on spheres with diameters ranging from 300 nm to 620 nm. Sum frequency generation spectroscopy in biosensors technology. Sum frequency generation sfg has been used for molecularlevel investigations of adsorbates under both ultrahigh vacuum and highpressure catalytic reaction conditions to characterize several important catalytic reactions on platinum single crystals. Sfs relies on the nonlinear optical phenomenon of sum frequency generation sfg.
Sum frequency generation spectroscopy is used to analyze surfaces and interfaces. Complex chi2 spectra of airwater interfaces in the presence of charged surfactants were measured by heterodynedetected broadband vibrational sum. An electronically enhanced chiral sum frequency generation. George j holinga sum frequency generation sfg vibrational spectroscopy was used to investigate the interfacial properties of several amino acids, peptides, and proteins adsorbed at the hydrophilic. Sum frequency generation spectroscopy sfg is a nonlinear laser spectroscopy technique used to analyze surfaces and interfaces. Sum frequency generation sfg vibrational spectroscopy.
Quantitative spectral and orientational analysis in surface. This book provides some examples of the use of vibrational spectroscopy in supramolecular chemistry, inorganic chemistry, solid state physics, but also in the fields of moleculebased materials or organic. Sum frequency generation vibrational spectroscopy sfg category. Ultrafast infrared vibrational spectroscopy 1st edition. Sfg spectroscopy is widely used as a powerful tool of surface characterization, although theoretical interpretation of the obtained spectra has been a major bottleneck for most users. This book provides some examples of the use of vibrational spectroscopy in supramolecular chemistry, inorganic chemistry, solid state physics, but also in the fields of moleculebased materials or organicinorganic interfaces. Here we introduce vibrational sumfrequency generation sfg spectroscopy, a nonlinear optical technique that is capable to selectively probe molecules at interfaces. Quantitative spectral and orientational analysis in surface sum frequency generation vibrational spectroscopy sfgvs hongfei wang, wei ganyz,rongluyzx, yi raoyz and baohua wuy state key laboratory of molecular reaction dynamics, institute of chemistry, the chinese academy of sciences, zhongguancun, beijing, pr china 80. Sum frequency generation vibrational spectroscopy using. A compact optical microscope was constructed with totalinternal reflection tir sfg geometry to monitor the tightly focused sfg laser spots on interfaces, providing the capability of selectively probing different regions on heterogeneous biointerfaces. Sumfrequency generation vibrational spectroscopy is a secondorder.
Vibrational sum frequency generation spectroscopy of. Sum frequency generation vibrational spectroscopy sfgvs has been proven to be a uniquely effective spectroscopic technique in the investigation of molecular structure and conformations, as well as the dynamics of molecular interfaces. Vibrational sumfrequency generation vsfg spectroscopy is a powerful tool to study interfaces. Sum frequency generation sfg vibrational spectroscopy has important applications in studying surface molecular structures. This is the novel idea of using surface for spectroscopy studies. Sum frequency generation vibrational spectroscopy for. Computational analysis of vibrational sum frequency. Differential uranylv oxogroup bonding between the uranium and metal cations from groups 1, 2, 4, and 12. Theory of sum frequency generation spectroscopy akihiro morita. Theory of sum frequency generation spectroscopy akihiro. Sum frequency generation spectroscopy in biosensors. T1 surface vibrational spectroscopy by infraredvisible sum frequency generation.
Surfaceenhanced irvisible sum frequency generation. Sum frequency generation vibrational spectroscopy studies. Sfg spectroscopy is widely used as a powerful tool of surface characterization, although theoretical interpretation of the obtained spectra has been a. The aim of the dissertation was to show that the complex surface analytical. A compact optical microscope was constructed with totalinternal reflection tir sfg geometry to monitor the tightly focused sfg laser spots on interfaces, providing the capability of selectively probing different regions on heterogeneous. Sum frequency generation vibrational spectroscopy of adsorbed amino acids, peptides, and proteins at hydrophilic and hydrophobic solidwater interfaces. This book mainly focuses on the study of the interfacial water by using molecular dynamics simulation and experimental sum frequency generation spectroscopy.
The pyriform silk molecular orientation of the attachment disc of a spider was studied using infraredvisible vibrational sum frequency generation sfg spectroscopy. With the rapid development of materials science, ondemand techniques are highly needed with the capability to characterize materials in the micrometer and nanometer scales. This book focuses on the study of the interfacial water using molecular dynamics simulation and experimental sum frequency generation spectroscopy. Sum frequency generation vibrational spectroscopy of adsorbed. Sum frequency generation vibrational spectroscopy sfs is a surfacespeci. In a typical sfg setup, two laser beams mix at an interface and generate an output beam with a frequency equal to the sum of the two input frequencies, traveling in a direction given by the sum of the incident beams wavevectors. Theoretical sum frequency generation spectroscopy of peptides. Vibrational sumfrequency generation spectroscopy is a powerful method for the study of fast dynamics at the airwater interface, but. Sumfrequency generation spectroscopy of biointerfaces. Practically, in a sfg experiment, two pulsed laser beams one in the infrared and the. An electronically enhanced chiral sum frequency generation vibrational spectroscopy study of lipidbound cytochrome c k. N2 we report the first observation of a vibrational spectrum of a monolayer of molecular adsorbates by infraredvisible sum. Jun 18, 2012 vibrational sum frequency generation spectroscopy of the water liquidvapor interface from density functional theorybased molecular dynamics simulations.
Vibrational sum frequency generation spectroscopy springerlink. The sum frequency generation sfg spectrum from the water1,2. Sum frequency generation spectroscopy sfg is a technique used to analyze surfaces and interfaces. Sum frequency generation sfg spectroscopy is an experimental technique for differentiating between various conformations and orientations of interfacial proteins. Infraredvisible sum frequency generation sfg vibrational spectroscopy offers another solution as it directly extracts the vibrational information from the surface or the interface with no, or only minor, perturbation from the surrounding bulk. Sum frequency generation vibrational spectroscopy sfgvs, a surface specific nonlinear optical spectroscopic technique, first developed in the late 1980s, has gradually advanced into one of the most powerful tools to characterize buried interfaces in situ. Introduction to surface chemistry and catalysis 2, somorjai. Sum frequency generation vibrational spectroscopy is a nonlinear optical spectroscopic technique to analyze surfaces and interfaces, including those of biological relevance. Molecular dynamics simulation study yuki nagata and shaul mukamel university of california, irvine, california 92617 received january 20, 2010. Herein, we present a perspective on the use of vibrational sumfrequency generation vsfg spectroscopy to study such electrocatalytic mechanisms. Implementing the theory of sum frequency generation. The spectra may be analysed to provide the polar orientation, molecular conformation, and average tilt angle of the adsorbate to the surface normal. New insights from sum frequency generation vibrational.
Recently, multiplex heterodynedetected vsfg hdvsfg has been developed, which enables the direct. Timedependent vibrational sumfrequency generation spectroscopy of the air water interface. Vibrational sum frequency generation sfg spectroscopy offers an attractive alternative to these techniques because of its intrinsic surface selectivity described below, which obviates the need for vesicles or desolvated systems, and its fast dynamical time scale. Timedependent vibrational sumfrequency generation spectroscopy. Download it once and read it on your kindle device, pc, phones or tablets. Combining a theoretical framework for sfg with molecular dynamics md simulations provides a powerful tool for studying systems containing interfacial proteins with applications in cell transport, biofilms. A sum frequency generation sfg vibrational micro spectroscopy system was developed to examine buried heterogeneous biointerfaces. It proposes a new definition of the free oh groups at waterair interface and presents research on the structure and dynamics of these groups.
Infraredvisible sumfrequency generation sfg vibrational spectroscopy offers another solution as it directly extracts the vibrational information from the surface or the interface with no, or only minor, perturbation from the surrounding bulk. Sum frequency generation sfg vibrational spectroscopy was used to investigate the interfacial properties of several amino acids, peptides, and proteins adsorbed at the hydrophilic polystyrene solidliquid and the hydrophobic silica solidliquid interfaces. Sum frequency generation vibrational spectroscopy sfs is a non. Sum frequency generation vibrational spectroscopy sfgvs has. Many ultrafast techniques including vibrational sum frequency generation sfg are developing in a rapid pace, however very little academic literature exists on how to best utilize this novel techniques towards real life applications. Surfaceenhanced ir visible sum frequency generation sfg was studied using ag and au films over nanospheres agfon and aufon, which provided large area of reproducible nanoscale structures with welldefined morphology.
An electronically enhanced chiral sum frequency generation vibrational spectroscopy study of lipidbound cytochrome c. Introduction to quantitative data analysis in vibrational sum. The first book on the topic, and written by the founder of the technique, this comprehensive resource provides a detailed overview of sumfrequency spectroscopy, its fundamental principles, and the wide range of applications for surfaces, interfaces, and bulk. Elsevier surface science 377379 1997 10711075 surface science vibrational investigation of chemisorbed c6o by infraredvisible sum frequency generation spectroscopy y. The vsfg spectra on sio 2 and caf 2 exhibit notably different intensities for the f 1u and a g vibrational modes. Quantitative sumfrequency generation vibrational spectroscopy of. Novel polymer materials have been developed to help reduce biofouling. Vibrational sumfrequency generation spectroscopy at the. Here we introduce vibrational sum frequency generation sfg spectroscopy, a nonlinear optical technique that is capable to selectively probe molecules at interfaces. Sum frequency generation vibrational spectroscopy sfgvs is an insitu, nondestructive, and nonlinear laser spectroscopic method that provides unique opportunities to probe molecular interactions on surfaces and buried interfaces, owing to its high interface selectivity and sensitivity. Characterization tools sum frequency generation vibrational spectroscopy sfgvs is an insitu, nondestructive, and nonlinear laser spectroscopic method that provides unique opportunities to probe molecular interactions on surfaces and buried interfaces, owing to its high interface selectivity and sensitivity. Surfaceenhanced irvisible sum frequency generation sfg was studied using ag and au films over nanospheres agfon and aufon, which provided large area of reproducible nanoscale structures with welldefined morphology. Multireflection sum frequency generation vibrational spectroscopy. Surface vibrational spectroscopy by infraredvisible sum.
Introduction to quantitative data analysis in vibrational. Vibrational sumfrequency generation spectroscopy at the waterlipid interface. Sum frequency generation sfg vibrational spectroscopy is a nonlinear optical vibrational spectroscopy, which has been shown to have submonolayer surface sensitivity. Sum frequency generation vibrational spectroscopy sfgvs is an insitu, nondestructive, and nonlinear. Vibrational sumfrequency generation spectroscopy of electrode.
Sfg spectroscopy can be applied under ex vacuo conditions and allows to record vibrational spectra from molecules at interfaces. The book proposes a new definition of the free oh groups. Theory of sum frequency generation spectroscopy ebook. The journal of physical chemistry letters 20, 4 1, 8387. In this work, we show that, by employing a prism geometry, total internal reflection sum frequency generation sfg vibrational spectroscopy allows for characterizing mesoscopic materials with irregular or. Ultrafast processes at liquid interfaces investigated with timeresolved sum frequency generation.
The sumfrequency generation sfg spectrum from the water1,2. When a spider secretes attachment disc silk, its spinnerets are said to rub backandforth on parallel straight lines and pyriform silk molecules are forced to be oriented. The results pave the way for future dynamic studies of surface. Vibrational sum frequency generation spectroscopy at the waterlipid interface. We describe here general descriptions of lipidbased gene therapy and vibrational sum frequency generation vsfg spectroscopy. Sum frequency generation sfg vibrational spectroscopy has been employed to study a variety of interesting biological phenomena occurring at interfaces. A theoretical description of the vibrational sum frequency. Sum frequency generation vibrational spectroscopy sfgvs is powerful and versatile method for insitu investigation of surfaces and interfaces. Although vsfg spectroscopy can sensitively detect molecular details of interfaces, interpretation of observed spectra has, until recently, been challenging and often ambiguous. Sum frequency generation vibrational spectroscopy sfgvs can provide detailed information and understanding of the molecular composition, interactions, and orientational and conformational structure of surfaces and interfaces through quantitative measurement and analysis. The technique relies on a secondorder nonlinear optical process forbidden in centrosymmetric media.
This book describes fundamental theory and recent advances of sum frequency generation sfg spectroscopy. Energy transport in molecules studied by relaxationassisted 2d ir spectroscopy. A theoretical description of the vibrational sum frequency generation spectroscopy of interfaces angela s. Homogeneous and inhomogeneous broadenings and the voigt line shapes in the phaseresolved and intensity sumfrequency generation vibrational spectroscopy. Vis beam to produce an output at the sum frequency. The vibrational spectroscopies spectroscopy in catalysis. As it is known, the ir or raman spectra of large molecules are complicated and difficult to analyze. Introduction to surface chemistry and catalysis kindle edition by somorjai, gabor a. Sum frequency generation vibrational spectroscopy sfg.
Sumfrequency generation vibrational spectroscopy sfgvs can provide detailed information and understanding of the molecular composition, interactions, and orientational and conformational structure of surfaces and interfaces through quantitative measurement and analysis. A sum frequency generation sfg vibrational microspectroscopy system was developed to examine buried heterogeneous biointerfaces. Sfg spectroscopy can be applied under ex vacuo conditions and allows to record vibrational spectra from molecules at. Complex chi2 spectra of airwater interfaces in the presence of charged surfactants were measured by heterodynedetected broadband vibrational sum frequency generation spectroscopy for the first. For advanced readers, this book covers recent developments in insitu surface analysis such as high pressure scanning tunneling microscopy, ambient pressure xray photoelectron spectroscopy, and sum frequency generation vibrational spectroscopy sfg. Osa sum frequency generation vibrational spectroscopic. Sum frequency generation vibrational spectroscopy sfgvs is an insitu, non destructive, and nonlinear. N2 we report the first observation of a vibrational spectrum of a monolayer of molecular adsorbates by infraredvisible sum frequency generation. Vibrational sum frequency generation spectroscopy request pdf. Although vsfg spectroscopy can sensitively detect molecular details of interfaces, interpretation of observed spectra has, until recently, been challenging and often.
The use of sfg vibrational spectroscopy enables researchers to probe the reactions at the. The theoretical topics are treated at basic levels. Sum frequency generation spectroscopy uses two laser beams mixed at a surface to generate an output beam with a frequency equal to the sum of the two input frequencies. Ultrafast spectroscopic techniques provide invaluable information in understanding complex surface phenomena. Sum frequency generation vibrational spectroscopy sfgvs for. Basic theory of surface sumfrequency generation the. These shall provide a novel perspective on the understanding of sfgvs not only.
Vibrational investigation of chemisorbed c60 by infrared. Sum frequency generation sfg vibrational spectroscopy, a secondorder nonlinear optical technique, occurs at a surface or interface where the inversion symmetry is broken under the electricdipole approximation. Also, as sum frequency generation occurs over a longer and longer length, the phasematching must become more and more accurate. Theory of sum frequency generation spectroscopy springerlink. Sum frequency generation vibrational spectroscopy sfgvs for complex. Part of theamerican studies commons this dissertation is brought to you for free and open access by the graduate school at scholar. Sfg vibrational spectra for a selfassembled monolayer of octadecanethiol were investig.
Recently, an emerging technique, sum frequency generation vibrational sfg spectroscopy was applied to the analysis of proteins adsorbed at various interfaces. Quantitative spectral and orientational analysis in. Investigation of interfaces by sum frequency generation vibrational spectroscopy tunneling microscopy stm together with sum frequency generation spectroscopy we have studied the surfaces and the processes at the interfaces. Sum frequency generation vibrational spectroscopy of. Use features like bookmarks, note taking and highlighting while reading introduction to. Timedependent vibrational sumfrequency generation spectroscopy of the airwater interface. Sum frequency generation vibrational spectroscopy sfg hymarc.
Aug 02, 2018 this book describes fundamental theory and recent advances of sum frequency generation sfg spectroscopy. Sum frequency generation sfg is one of the secondorder nonlinear optical processes in which two incident photons are upconverted to one photon having the energy frequency of the sum of these two inputs shen in the principles of nonlinear optics. Investigation of interfaces by sumfrequency generation. When the visible and infrared pulses overlap in time and space. Sum frequency generation spectroscopy study of the. Vibrational sum frequency generation vsfg spectroscopy is a widely used probe of interfaces and, having ideal surface sensitivity and selectivity, is particularly powerful when applied to wet and soft interfaces. The infrared and raman spectroscopy have applications in numerous fields, namely chemistry, physics, astronomy, biology, medicine, geology, mineralogy etc. Sum frequency generation vibrational spectroscopy studies on. It was devoloped in to a surface specific vibrational spectroscopy in 1987 by the groups of shen and harris.
Sum frequency generation vibrational spectroscopy springerlink. Characterization tools sum frequency generation vibrational spectroscopy sfgvs is an insitu, nondestructive, and nonlinear laser spectroscopic method that provides unique opportunities to probe molecular interactions on surfaces and buried interfaces, owing to its high interface selectivity and. Vibrational sum frequency generation vsfg spectroscopy was used to measure the interfacial spectra of fullerene thin films on dielectric substrates that are commonly used in ir spectroscopy. Structures and dynamics of interfacial water input from. Vibrational energy and molecular thermometers in liquids. This chapter describes recent advances in vibrational sum frequency generation sfg instrumentation.